Issue 23, 2013
From the journal:

CrystEngComm

Lanthanide-containing peroxoisopolytungstate with tetrahedral WO42− template core, [Ln4(WO4)(H2O)16{W7O22(O2)2}4]14−†

Lanying Song,a   Dongdi Zhang,a   Pengtao Ma,a   Zhijie Liang,a   Jingping Wang*a  and  Jingyang Niu*a  

* Corresponding authors

a Henan Key Laboratory of Polyoxometalate, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan 475004, China
E-mail: jpwang@henu.edu.cn, jyniu@henu.edu.cn
Fax: +86 378-3886876

Abstract

Two lanthanide-containing peroxoisopolyanions [Ln4(WO4)(H2O)16{W7O22(O2)2}4]14− (Ln = LaIII; PrIII), have been synthesized by reaction of Na2WO4 and lanthanide (Ln) ions in the presence of peroxide. These represent the first two examples of peroxo-containing Ln-stabilized polyanions (LSPs), and have the highest number of W atoms among all known Ln-stabilized isopolytungstates (IPTs) as well.

Graphical abstract: Lanthanide-containing peroxoisopolytungstate with tetrahedral WO42− template core, [Ln4(WO4)(H2O)16{W7O22(O2)2}4]14−

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Article information

DOI
https://doi.org/10.1039/C3CE40343B
Article type
Communication
Submitted
24 Feb 2013
Accepted
05 Apr 2013
First published
08 Apr 2013

CrystEngComm, 2013,15, 4597-4600

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Lanthanide-containing peroxoisopolytungstate with tetrahedral WO42− template core, [Ln4(WO4)(H2O)16{W7O22(O2)2}4]14−

L. Song, D. Zhang, P. Ma, Z. Liang, J. Wang and J. Niu, CrystEngComm, 2013, 15, 4597 DOI: 10.1039/C3CE40343B

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