Issue 4, 2013

Enhancing CO2adsorption enthalpy and selectivity viaamino functionalization of a tetrahedral framework material

Abstract

The cooperative assembly of mixed 2-aminoisonicotinate and adeninate ligands with Zn2+ centers generates a porous tetrahedral framework material with rich amino groups in the pores, which shows high CO2 uptake at 0.1 bar, high enthalpy of CO2 adsorption (40 kJ mol−1) and excellent adsorption selectivity of CO2 over N2 under ambient conditions.

Graphical abstract: Enhancing CO2 adsorption enthalpy and selectivity via amino functionalization of a tetrahedral framework material

Supplementary files

Article information

Article type
Communication
Submitted
03 Oct 2012
Accepted
13 Nov 2012
First published
14 Nov 2012

CrystEngComm, 2013,15, 658-661

Enhancing CO2 adsorption enthalpy and selectivity via amino functionalization of a tetrahedral framework material

E. Yang, H. Li, F. Wang, H. Yang and J. Zhang, CrystEngComm, 2013, 15, 658 DOI: 10.1039/C2CE26612A

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