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Issue 10, 2014
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Enantioselective Black rearrangement catalyzed by chiral bicyclic imidazole

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Abstract

A newly developed chiral imidazole nucleophilic catalyst, Acyloxy-DPI, was readily prepared and successfully applied to the enantioselective Black rearrangement with up to 88% ee for a wide range of substrates possessing different substituted groups. A plausible mechanism for the high enantioselectivity was proposed.

Graphical abstract: Enantioselective Black rearrangement catalyzed by chiral bicyclic imidazole

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Publication details

The article was received on 29 Sep 2013, accepted on 21 Nov 2013 and first published on 26 Nov 2013


Article type: Communication
DOI: 10.1039/C3CC47455K
Citation: Chem. Commun., 2014,50, 1227-1230
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    Enantioselective Black rearrangement catalyzed by chiral bicyclic imidazole

    M. Wang, Z. Zhang, S. Liu, F. Xie and W. Zhang, Chem. Commun., 2014, 50, 1227
    DOI: 10.1039/C3CC47455K

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