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Issue 98, 2013
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Site specific carboxylation of abnormal anionic N-heterocyclic dicarbenes with CO2

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Abstract

Herein, we report experimental and computational results for the carboxylation of abnormal anionic N-heterocyclic dicarbenes (NHDCs) with CO2. Under ambient dosing conditions, carbonyl addition occurs selectively at C4 without a second carboxylation event occurring at the C2 carbene center.

Graphical abstract: Site specific carboxylation of abnormal anionic N-heterocyclic dicarbenes with CO2

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Publication details

The article was received on 27 Aug 2013, accepted on 08 Oct 2013 and first published on 31 Oct 2013


Article type: Communication
DOI: 10.1039/C3CC46555A
Citation: Chem. Commun., 2013,49, 11527-11529
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    Site specific carboxylation of abnormal anionic N-heterocyclic dicarbenes with CO2

    M. Vogt, C. Wu, A. G. Oliver, C. J. Meyer, W. F. Schneider and B. L. Ashfeld, Chem. Commun., 2013, 49, 11527
    DOI: 10.1039/C3CC46555A

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