Issue 96, 2013
From the journal:

Chemical Communications

Pd-catalyzed synthesis of symmetrical and unsymmetrical siloxanes†

Yu Kurihara,a   Yoshinori Yamanoi*a  and  Hiroshi Nishihara*a  

* Corresponding authors

a Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan
E-mail: yamanoi@chem.s.u-tokyo.ac.jp, nisihara@chem.s.u-tokyo.ac.jp
Fax: +81 3 5841 8063
Tel: +81 3 5841 4346

Abstract

A palladium-catalyzed arylation of hydrosiloxanes was developed for the synthesis of symmetrical and unsymmetrical siloxanes. Reactive functional moieties such as hydroxy or cyano groups were able to tolerate the reaction conditions and several novel unsymmetrical siloxanes were synthesized in moderate to high yield.

Graphical abstract: Pd-catalyzed synthesis of symmetrical and unsymmetrical siloxanes

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Article information

DOI
https://doi.org/10.1039/C3CC46294C
Article type
Communication
Submitted
16 Aug 2013
Accepted
10 Oct 2013
First published
10 Oct 2013

Chem. Commun., 2013,49, 11275-11277

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Pd-catalyzed synthesis of symmetrical and unsymmetrical siloxanes

Y. Kurihara, Y. Yamanoi and H. Nishihara, Chem. Commun., 2013, 49, 11275 DOI: 10.1039/C3CC46294C

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