Issue 89, 2013
From the journal:

Chemical Communications

Probing secondary coordination sphere influence on the oxygenation of zinc alkyls: formation of a unique zinc peroxide species†

Piotr Sobota,*a   Rafał Petrus,a   Karolina Zelga,b   Łukasz Mąkolski,b   Dominik Kubickib  and  Janusz Lewiński*bc  

* Corresponding authors

a Faculty of Chemistry, University of Wrocław, 14 F. Joliot-Curie St., 50-383 Wrocław, Poland
E-mail: plas@stud.chem.uni.wroc.pl

b Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw, Poland
E-mail: lewin@ch.pw.edu.pl
Fax: +48-22-234-7279

c Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland

Abstract

Reactions of ethylzinc derivatives of o-hydroxybiphenyl with O2 were investigated. The study revealed an essential role in the oxygenation process of intra-molecular interactions involving aromatic rings and provided a unique aryloxide (hydroxide) Zn8(OAr)8(OH)6(O2) cluster with an encapsulated peroxide species.

Graphical abstract: Probing secondary coordination sphere influence on the oxygenation of zinc alkyls: formation of a unique zinc peroxide species

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Article information

DOI
https://doi.org/10.1039/C3CC46206D
Article type
Communication
Submitted
13 Aug 2013
Accepted
17 Sep 2013
First published
17 Sep 2013

Chem. Commun., 2013,49, 10477-10479

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Probing secondary coordination sphere influence on the oxygenation of zinc alkyls: formation of a unique zinc peroxide species

P. Sobota, R. Petrus, K. Zelga, Ł. Mąkolski, D. Kubicki and J. Lewiński, Chem. Commun., 2013, 49, 10477 DOI: 10.1039/C3CC46206D

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