Issue 88, 2013
From the journal:

Chemical Communications

Silver-catalyzed oxidative coupling/cyclization of acrylamides with 1,3-dicarbonyl compounds†

Hua Wang,a   Li-Na Guo*a  and  Xin-Hua Duan*a  

* Corresponding authors

a Department of Chemistry, School of Science and MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter, Xi'an Jiaotong University, Xi'an 710049, China
E-mail: duanxh@mail.xjtu.edu.cn, guoln81@mail.xjtu.edu.cn

Abstract

An efficient silver-catalyzed oxidative cyclization of acrylamides with 1,3-dicarbonyl compounds is described. It proceeds through a tandem radical addition/cyclization process, in which two new C–C bonds were formed. Furthermore, the same concept can also be extended to the reaction of easily available ketones and acrylamides.

Graphical abstract: Silver-catalyzed oxidative coupling/cyclization of acrylamides with 1,3-dicarbonyl compounds

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Article information

DOI
https://doi.org/10.1039/C3CC46114A
Article type
Communication
Submitted
10 Aug 2013
Accepted
12 Sep 2013
First published
25 Sep 2013

Chem. Commun., 2013,49, 10370-10372

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Silver-catalyzed oxidative coupling/cyclization of acrylamides with 1,3-dicarbonyl compounds

H. Wang, L. Guo and X. Duan, Chem. Commun., 2013, 49, 10370 DOI: 10.1039/C3CC46114A

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