Issue 82, 2013

Identification of bridged CO2 binding in a Prussian blue analogue using neutron powder diffraction

Abstract

Neutron powder diffraction measurements were carried out on the evacuated and CO2-loaded Prussian blue analogue, Fe3[Co(CN)6]2, identifying two distinct CO2 adsorption sites: site A, in which CO2 uniquely bridges between two bare-metal sites, and site B, in which it interacts in a face capping motif. The saturation of site A at low loadings of CO2 demonstrates the favourable nature of the interaction of CO2 with bare-metal sites within the material.

Graphical abstract: Identification of bridged CO2 binding in a Prussian blue analogue using neutron powder diffraction

Supplementary files

Article information

Article type
Communication
Submitted
07 Aug 2013
Accepted
30 Aug 2013
First published
02 Sep 2013

Chem. Commun., 2013,49, 9404-9406

Identification of bridged CO2 binding in a Prussian blue analogue using neutron powder diffraction

S. H. Ogilvie, S. G. Duyker, P. D. Southon, V. K. Peterson and C. J. Kepert, Chem. Commun., 2013, 49, 9404 DOI: 10.1039/C3CC46019C

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