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Issue 84, 2013
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Structural and theoretical studies of intermolecular dihydrogen bonding in [(C6F5)2(C6Cl5)B]–H⋯H–[TMP]

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Abstract

The product of the intermolecular ‘frustrated Lewis pair’ (FLP) B(C6F5)2(C6Cl5)/2,2,6,6-tetramethylpiperidine and H2 has been studied by single-crystal neutron diffraction. This is the first structurally characterised example of a geometrically unconstrained dihydrogen (H⋯H) bond within a hydrogenated FLP system.

Graphical abstract: Structural and theoretical studies of intermolecular dihydrogen bonding in [(C6F5)2(C6Cl5)B]–H⋯H–[TMP]

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Publication details

The article was received on 01 Aug 2013, accepted on 09 Sep 2013 and first published on 16 Sep 2013


Article type: Communication
DOI: 10.1039/C3CC45889J
Citation: Chem. Commun., 2013,49, 9755-9757
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    Structural and theoretical studies of intermolecular dihydrogen bonding in [(C6F5)2(C6Cl5)B]–H⋯H–[TMP]

    H. Zaher, A. E. Ashley, M. Irwin, A. L. Thompson, M. J. Gutmann, T. Krämer and D. O'Hare, Chem. Commun., 2013, 49, 9755
    DOI: 10.1039/C3CC45889J

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