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Issue 80, 2013
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Can heterometallic 1-dimensional chains support current rectification?

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Abstract

To what extent can a heterometallic chain of transition metal ions generate an asymmetric current–voltage response? Density functional theory suggests that the answer depends very much on the symmetry of the dominant conduction channel: π channels are more localised and hence afford higher rectification ratios.

Graphical abstract: Can heterometallic 1-dimensional chains support current rectification?

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Publication details

The article was received on 09 Jul 2013, accepted on 22 Aug 2013 and first published on 22 Aug 2013


Article type: Communication
DOI: 10.1039/C3CC45063E
Citation: Chem. Commun., 2013,49, 9116-9118
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    Can heterometallic 1-dimensional chains support current rectification?

    D. DeBrincat, O. Keers and J. E. McGrady, Chem. Commun., 2013, 49, 9116
    DOI: 10.1039/C3CC45063E

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