Jump to main content
Jump to site search
PLANNED MAINTENANCE Close the message box

Scheduled maintenance upgrade on Thursday 4th of May 2017 from 8.00am to 9.00am (BST).

During this time our websites will be offline temporarily. If you have any questions please use the feedback button on this page. We apologise for any inconvenience this might cause and thank you for your patience.


Issue 84, 2013
Previous Article Next Article

Pillar substitution modulates CO2 affinity in “mmo” topology networks

Author affiliations

Abstract

The use of WO42− instead of CrO42− or MoO42− as an angular pillar in mmo topology nets has afforded two isostructural porous nets of formula [M(bpe)2WO4] (M = Co or Ni, bpe = 1,2-(4-pyridyl)ethene). The Ni variant, WOFOUR-1-Ni, is highly selective towards CO2 thanks to its exceptionally high isosteric heat of adsorption (Qst) of −65.5 kJ mol−1 at zero loading.

Graphical abstract: Pillar substitution modulates CO2 affinity in “mmo” topology networks

Back to tab navigation
Please wait while Download options loads

Supplementary files

Publication details

The article was received on 24 Jun 2013, accepted on 04 Sep 2013 and first published on 05 Sep 2013


Article type: Communication
DOI: 10.1039/C3CC44745F
Citation: Chem. Commun., 2013,49, 9809-9811
  •   Request permissions

    Pillar substitution modulates CO2 affinity in “mmo” topology networks

    M. H. Mohamed, S. K. Elsaidi, T. Pham, K. A. Forrest, B. Tudor, L. Wojtas, B. Space and M. J. Zaworotko, Chem. Commun., 2013, 49, 9809
    DOI: 10.1039/C3CC44745F

Search articles by author