Issue 67, 2013
From the journal:

Chemical Communications

Reaction of trisubstituted alkenes with iron porphyrin carbenes: facile synthesis of tetrasubstituted dienes and cyclopentadienes†

Peng Wang,a   Saihu Liao,a   Sunewang R. Wang,a   Run-Duo Gaoa  and  Yong Tang*a  

* Corresponding authors

a State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, China
E-mail: tangy@sioc.ac.cn

Abstract

The unprecedented reaction of trisubstituted alkenes with iron porphyrin carbenes has been successfully developed. Both multiply substituted 1,3-butadiene and cyclopentadiene products are readily accessible with high efficiency and selectivity in good yields.

Graphical abstract: Reaction of trisubstituted alkenes with iron porphyrin carbenes: facile synthesis of tetrasubstituted dienes and cyclopentadienes

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Article information

DOI
https://doi.org/10.1039/C3CC44092C
Article type
Communication
Submitted
31 May 2013
Accepted
22 Jun 2013
First published
24 Jun 2013

Chem. Commun., 2013,49, 7436-7438

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Reaction of trisubstituted alkenes with iron porphyrin carbenes: facile synthesis of tetrasubstituted dienes and cyclopentadienes

P. Wang, S. Liao, S. R. Wang, R. Gao and Y. Tang, Chem. Commun., 2013, 49, 7436 DOI: 10.1039/C3CC44092C

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