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Issue 72, 2013
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A Lewis acid catalytic core sandwiched by inorganic polyoxoanion caps: selective H2O2-based oxidations with [AlIII4(H2O)10(β-XW9O33H)2]6− (X = AsIII, SbIII)

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Abstract

The AlIII-containing polyanions [AlIII4(H2O)10(β-XW9O33H)2]4− with X = AsIII (1) and SbIII (2) feature four aluminum(III) centers sandwiched by two trivacant (β-XW9O33) Keggin units, and trigger peroxide catalysis as well as substrate coordination via multiple Lewis acid site interactions.

Graphical abstract: A Lewis acid catalytic core sandwiched by inorganic polyoxoanion caps: selective H2O2-based oxidations with [AlIII4(H2O)10(β-XW9O33H)2]6− (X = AsIII, SbIII)

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Publication details

The article was received on 30 May 2013, accepted on 27 Jun 2013 and first published on 28 Jun 2013


Article type: Communication
DOI: 10.1039/C3CC44077J
Citation: Chem. Commun., 2013,49, 7914-7916
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    A Lewis acid catalytic core sandwiched by inorganic polyoxoanion caps: selective H2O2-based oxidations with [AlIII4(H2O)10(β-XW9O33H)2]6− (X = AsIII, SbIII)

    M. Carraro, B. S. Bassil, A. Sorarù, S. Berardi, A. Suchopar, U. Kortz and M. Bonchio, Chem. Commun., 2013, 49, 7914
    DOI: 10.1039/C3CC44077J

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