Issue 67, 2013
From the journal:

Chemical Communications

Ionic conductivity of [Li+@C60](PF6−) in organic solvents and its electrochemical reduction to Li+@C60˙−

Hiroshi Ueno,a   Ken Kokubo,*a   Yuji Nakamura,a   Kei Ohkubo,b   Naohiko Ikuma,a   Hiroshi Moriyama,c   Shunichi Fukuzumibd  and  Takumi Oshimaa  

* Corresponding authors

a Division of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan
E-mail: kokubo@chem.eng.osaka-u.ac.jp
Fax: +81-6-6879-4593
Tel: +81-6-6879-4592

b Department of Material and Life Science, Graduate School of Engineering, Osaka University, and ALCA, Japan Science and Technology (JST), Suita, Osaka 565-0871, Japan

c Department of Chemistry, Faculty of Science, Toho University, 2-2-1 Miyama, Funabashi, Chiba 274-8510, Japan

d Department of Bioinspired Science, Ewha Womans University, Seoul, Korea

Abstract

The ionic conductivity of [Li+@C60](PF6−) was measured in o-dichlorobenzene, and found to be higher than that of TBA+PF6−. Electrochemical reduction of [Li+@C60](PF6−) without any supporting electrolyte gave the monovalent radical anion Li+@C60˙−, as confirmed by the characteristic ESR signal and NIR absorption band.

Graphical abstract: Ionic conductivity of [Li+@C60](PF6−) in organic solvents and its electrochemical reduction to Li+@C60˙−

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Article information

DOI
https://doi.org/10.1039/C3CC43901A
Article type
Communication
Submitted
24 May 2013
Accepted
26 Jun 2013
First published
27 Jun 2013
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2013,49, 7376-7378

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Ionic conductivity of [Li+@C60](PF6−) in organic solvents and its electrochemical reduction to Li+@C60˙−

H. Ueno, K. Kokubo, Y. Nakamura, K. Ohkubo, N. Ikuma, H. Moriyama, S. Fukuzumi and T. Oshima, Chem. Commun., 2013, 49, 7376 DOI: 10.1039/C3CC43901A

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