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Issue 64, 2013
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Reversible carbon–carbon bond formation between carbonyl compounds and a ruthenium pincer complex

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Abstract

This communication describes the reversible reaction of a ruthenium pincer complex with a variety of carbonyl compounds. Both NMR spectroscopic and X-ray crystallographic characterization of isomeric carbonyl adducts are reported, and the equilibrium constants for carbonyl binding have been determined.

Graphical abstract: Reversible carbon–carbon bond formation between carbonyl compounds and a ruthenium pincer complex

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Publication details

The article was received on 10 May 2013, accepted on 21 Jun 2013 and first published on 05 Jul 2013


Article type: Communication
DOI: 10.1039/C3CC43517B
Citation: Chem. Commun., 2013,49, 7147-7149
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    Reversible carbon–carbon bond formation between carbonyl compounds and a ruthenium pincer complex

    C. A. Huff, J. W. Kampf and M. S. Sanford, Chem. Commun., 2013, 49, 7147
    DOI: 10.1039/C3CC43517B

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