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Issue 65, 2013
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The decisive role of ligand metathesis in Au/Pd bimetallic catalysis

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Abstract

AuClL1/PdCl2L22 cocatalyzed coupling of Ar1X and Ar2SnBu3 is feasible for bulky Ar1, provided that at least one ligand on Pd is not strongly coordinating. This can be achieved in situ by Au/Pd ligand exchange if L1 is weakly coordinating. When the exchange is slow, independent preparation of appropriate catalysts is recommended.

Graphical abstract: The decisive role of ligand metathesis in Au/Pd bimetallic catalysis

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Publication details

The article was received on 27 Apr 2013, accepted on 11 Jun 2013 and first published on 13 Jun 2013


Article type: Communication
DOI: 10.1039/C3CC43133A
Citation: Chem. Commun., 2013,49, 7246-7248
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    The decisive role of ligand metathesis in Au/Pd bimetallic catalysis

    J. delPozo, J. A. Casares and P. Espinet, Chem. Commun., 2013, 49, 7246
    DOI: 10.1039/C3CC43133A

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