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Issue 58, 2013
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Preparation of a semiquinonate-bridged diiron(II) complex and elucidation of its geometric and electronic structures

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Abstract

The synthesis and crystal structure of a diiron(II) complex containing a bridging semiquinonate radical are presented. The unique electronic structure of this S = 7/2 complex is examined with spectroscopic (absorption, EPR, resonance Raman) and computational methods.

Graphical abstract: Preparation of a semiquinonate-bridged diiron(ii) complex and elucidation of its geometric and electronic structures

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Publication details

The article was received on 22 Apr 2013, accepted on 01 Jun 2013 and first published on 03 Jun 2013


Article type: Communication
DOI: 10.1039/C3CC42980F
Citation: Chem. Commun., 2013,49, 6531-6533
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    Preparation of a semiquinonate-bridged diiron(II) complex and elucidation of its geometric and electronic structures

    A. E. Baum, S. V. Lindeman and A. T. Fiedler, Chem. Commun., 2013, 49, 6531
    DOI: 10.1039/C3CC42980F

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