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Issue 61, 2013
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Carbonylation of the simplest persistent diaminocarbene

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Abstract

The reactions of the acyclic diaminocarbenes (Me2N)2C and (Ph2N)(iPr2N)C with CO proceed in a 2 : 1 stoichiometric ratio, affording unprecedented betainic oxyallyl species of type [(R2N)2C]2CO.

Graphical abstract: Carbonylation of the simplest persistent diaminocarbene

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Publication details

The article was received on 18 Apr 2013, accepted on 11 May 2013 and first published on 13 May 2013


Article type: Communication
DOI: 10.1039/C3CC42888E
Citation: Chem. Commun., 2013,49, 6834-6836
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    Carbonylation of the simplest persistent diaminocarbene

    T. Schulz, C. Färber, M. Leibold, C. Bruhn, W. Baumann, D. Selent, T. Porsch, M. C. Holthausen and U. Siemeling, Chem. Commun., 2013, 49, 6834
    DOI: 10.1039/C3CC42888E

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