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Issue 50, 2013
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Electrochemical formation of MnIII-peroxo complexes supported by pentadentate amino pyridine and imidazole ligands

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Abstract

A novel and efficient method for preparing [MnIII(O2)(L)]+ complexes using electrochemically generated superoxide is reported, with the reaction probed by low temperature electronic absorption and electron paramagnetic resonance spectroscopic techniques.

Graphical abstract: Electrochemical formation of MnIII-peroxo complexes supported by pentadentate amino pyridine and imidazole ligands

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Publication details

The article was received on 19 Feb 2013, accepted on 30 Apr 2013 and first published on 30 Apr 2013


Article type: Communication
DOI: 10.1039/C3CC41300D
Citation: Chem. Commun., 2013,49, 5696-5698
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    Electrochemical formation of MnIII-peroxo complexes supported by pentadentate amino pyridine and imidazole ligands

    S. El Ghachtouli, H. Y. Vincent Ching, B. Lassalle-Kaiser, R. Guillot, D. F. Leto, S. Chattopadhyay, T. A. Jackson, P. Dorlet and E. Anxolabéhère-Mallart, Chem. Commun., 2013, 49, 5696
    DOI: 10.1039/C3CC41300D

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