Issue 35, 2013
From the journal:

Chemical Communications

A giant metallo-supramolecular cage encapsulating a single-molecule magnet†

Yu-Yang Li,a   Feng Gao,a   Jonathon E. Beves,a   Yi-Zhi Lia  and  Jing-Lin Zuo*a  

* Corresponding authors

a State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093, P. R. China
E-mail: zuojl@nju.edu.cn
Fax: +86-25-83314502
Tel: +86-25-83593893

Abstract

A giant metallo-supramolecular cage encapsulating a single-molecule magnet, [Ag42{Ho(W5O18)2}(t-BuC[triple bond, length as m-dash]C)28Cl4]OH, is prepared and structurally characterized. It shows an interesting “peanut-like” structure and remains intact in solution as demonstrated by NMR studies.

Graphical abstract: A giant metallo-supramolecular cage encapsulating a single-molecule magnet

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Article information

DOI
https://doi.org/10.1039/C3CC41237G
Article type
Communication
Submitted
16 Feb 2013
Accepted
14 Mar 2013
First published
15 Mar 2013

Chem. Commun., 2013,49, 3658-3660

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A giant metallo-supramolecular cage encapsulating a single-molecule magnet

Y. Li, F. Gao, J. E. Beves, Y. Li and J. Zuo, Chem. Commun., 2013, 49, 3658 DOI: 10.1039/C3CC41237G

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