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Issue 25, 2013
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Diastereomeric cyclic tris-allenes

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Abstract

Both diastereomers of the tris-allene, cyclododeca-1,2,5,6,9,10-hexaene have been obtained using a triple cyclopropylidene–allene rearrangement. On the NMR timescale, one has D3 symmetry, and is the smallest hydrocarbon synthesised to have this symmetry, and the second has C2 symmetry.

Graphical abstract: Diastereomeric cyclic tris-allenes

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Publication details

The article was received on 27 Nov 2012, accepted on 07 Feb 2013 and first published on 07 Feb 2013


Article type: Communication
DOI: 10.1039/C3CC40354H
Citation: Chem. Commun., 2013,49, 2497-2499
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    Diastereomeric cyclic tris-allenes

    H. H. Mustafa, M. S. Baird, J. R. Al Dulayymi and V. V. Tverezovskiy, Chem. Commun., 2013, 49, 2497
    DOI: 10.1039/C3CC40354H

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