Issue 27, 2013
From the journal:

Chemical Communications

A sodium manganese ferrocyanide thin film for Na-ion batteries

Tomoyuki Matsuda,a   Masamitsu Takachia  and  Yutaka Moritomo*ab  

* Corresponding authors

a Graduate School of Pure and Applied Science, University of Tsukuba, Tsukuba, Ibaraki 305-8571, Japan
E-mail: moritomo@sakura.cc.tsukuba.ac.jp

b Tsukuba Research Center for Interdisciplinary Materials Science (TIMS), University of Tsukuba, Tsukuba, Ibaraki 305-8571, Japan

Abstract

A thin film of sodium manganese ferrocyanide, Na1.32Mn[Fe(CN)6]0.83·3.5H2O, exhibits discharge capacity (= 109 mA h g−1) and discharge voltage (3.4 V in average) at 0.5 C against Na in aprotic solvent. The ex situ XRD experiments reveal that the host framework remains cubic without showing any structural phase transition during the charge process. The discharge property is discernible up to 40 C.

Graphical abstract: A sodium manganese ferrocyanide thin film for Na-ion batteries

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Article information

DOI
https://doi.org/10.1039/C3CC38839E
Article type
Communication
Submitted
10 Dec 2012
Accepted
03 Feb 2013
First published
04 Feb 2013

Chem. Commun., 2013,49, 2750-2752

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A sodium manganese ferrocyanide thin film for Na-ion batteries

T. Matsuda, M. Takachi and Y. Moritomo, Chem. Commun., 2013, 49, 2750 DOI: 10.1039/C3CC38839E

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