Issue 28, 2013
From the journal:

Chemical Communications

Reductive elimination: a pathway to low-valent aluminium species†

Chelladurai Ganesamoorthy,a   Sinah Loerke,a   Christian Gemel,a   Paul Jerabek,b   Manuela Winter,a   Gernot Frenking*b  and  Roland A. Fischer*a  

* Corresponding authors

a Inorganic Chemistry II, Ruhr-University Bochum, Universitätsstrasse 150, 44801 Bochum, Germany
E-mail: roland.fischer@rub.de

b Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Strasse, 35032 Marburg, Germany
E-mail: frenking@chemie.uni-marburg.de

Abstract

Compounds Cp*AlH2 (1) and Cp*2AlH (2) reductively eliminate Cp*H in benzene or toluene under reflux conditions to give Al(s) and AlCp*, respectively.

Graphical abstract: Reductive elimination: a pathway to low-valent aluminium species

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3CC38584A
Article type
Communication
Submitted
29 Nov 2012
Accepted
21 Jan 2013
First published
22 Jan 2013

Chem. Commun., 2013,49, 2858-2860

Permissions

Request permissions

Reductive elimination: a pathway to low-valent aluminium species

C. Ganesamoorthy, S. Loerke, C. Gemel, P. Jerabek, M. Winter, G. Frenking and R. A. Fischer, Chem. Commun., 2013, 49, 2858 DOI: 10.1039/C3CC38584A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements