Organic multishell isostructural host–guest crystals: fullerenes C60 inside a nitroxide open framework

David Bardelang; Michel Giorgi; Cédric Pardanaud; Virginie Hornebecq; Egon Rizzato; Paul Tordo; Olivier Ouari

doi:10.1039/C3CC00170A

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Organic multishell isostructural host–guest crystals: fullerenes C₆₀ inside a nitroxide open framework†

David Bardelang,*^a Michel Giorgi,^b Cédric Pardanaud,^c Virginie Hornebecq,^d Egon Rizzato,^a Paul Tordo^a and Olivier Ouari*^a

Author affiliations

* Corresponding authors

^a Aix-Marseille Université, CNRS, Institut de Chimie Radicalaire, UMR 7273, 13013 Marseille, France
E-mail: david.bardelang@univ-amu.fr, olivier.ouari@univ-amu.fr
Tel: +33 4 91 28 86 10

^b Aix-Marseille Université, CNRS, Spectropole, FR-1739, 13013 Marseille, France

^c Aix-Marseille Université, CNRS, Laboratoire PIIM, UMR-7345, 13013 Marseille, France

^d Aix-Marseille Université, CNRS, Laboratoire MADIREL, UMR-7246, 13013 Marseille, France

Abstract

The dinitroxide biradical bTbk crystallizes forming hexagonal open frameworks with one-dimensional corrugated channels filled with crystallization solvent. The large pockets constitutive of the channels allowed the inclusion of C₆₀ in the paramagnetic network. The rapidity and high fidelity of crystal growth were used to prepare isostructural multilayer host–guest crystals successively stained with C₆₀.

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Article information

DOI: https://doi.org/10.1039/C3CC00170A
Article type: Communication
Submitted: 08 Jan 2013
Accepted: 07 Mar 2013
First published: 07 Mar 2013

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Chem. Commun., 2013,49, 3519-3521

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Organic multishell isostructural host–guest crystals: fullerenes C₆₀ inside a nitroxide open framework

D. Bardelang, M. Giorgi, C. Pardanaud, V. Hornebecq, E. Rizzato, P. Tordo and O. Ouari, Chem. Commun., 2013, 49, 3519 DOI: 10.1039/C3CC00170A

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