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Issue 1, 2013
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A homoleptic tetravalent cerium silylamide

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Abstract

Treatment of Ce[N(SiHMe2)2]3(thf)2 with the chlorinating agents PhICl2, Ph3CCl or C2Cl6 gave the homoleptic Ce(IV) silylamide Ce[N(SiHMe2)2]4. When performed in the absence of donating (solvent) molecules, the trivalent cluster Ce5[N(SiHMe2)2]8Cl7 was isolated.

Graphical abstract: A homoleptic tetravalent cerium silylamide

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Publication details

The article was received on 10 Oct 2012, accepted on 05 Nov 2012 and first published on 05 Nov 2012


Article type: Communication
DOI: 10.1039/C2CC37404H
Citation: Chem. Commun., 2013,49, 87-89
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    A homoleptic tetravalent cerium silylamide

    A. R. Crozier, A. M. Bienfait, C. Maichle-Mössmer, K. W. Törnroos and R. Anwander, Chem. Commun., 2013, 49, 87
    DOI: 10.1039/C2CC37404H

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