Issue 1, 2013
From the journal:

Chemical Communications

A homoleptic tetravalent cerium silylamide†

Alan R. Crozier,a   Andre M. Bienfait,a   Cäcilia Maichle-Mössmer,b   Karl W. Törnroosa  and  Reiner Anwander*b  

* Corresponding authors

a Department of Chemistry, University of Bergen, Allégaten 41, Bergen, Norway

b Institut für Anorganische Chemie, Eberhard Karls Universität Tübingen, Auf der Morgenstelle 18, Tübingen, Germany
E-mail: reiner.anwander@uni-tuebingen.de
Fax: +49 7071 292436

Abstract

Treatment of Ce[N(SiHMe2)2]3(thf)2 with the chlorinating agents PhICl2, Ph3CCl or C2Cl6 gave the homoleptic Ce(IV) silylamide Ce[N(SiHMe2)2]4. When performed in the absence of donating (solvent) molecules, the trivalent cluster Ce5[N(SiHMe2)2]8Cl7 was isolated.

Graphical abstract: A homoleptic tetravalent cerium silylamide

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Article information

DOI
https://doi.org/10.1039/C2CC37404H
Article type
Communication
Submitted
10 Oct 2012
Accepted
05 Nov 2012
First published
05 Nov 2012

Chem. Commun., 2013,49, 87-89

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A homoleptic tetravalent cerium silylamide

A. R. Crozier, A. M. Bienfait, C. Maichle-Mössmer, K. W. Törnroos and R. Anwander, Chem. Commun., 2013, 49, 87 DOI: 10.1039/C2CC37404H

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