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Issue 49, 2013
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Dioxygen mediated conversion of {Fe(NO)2}9 dinitrosyl iron complexes to Roussin's red esters

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Abstract

The reactivity of a series of {Fe(NO)2}9 dinitrosyl iron complexes bearing thiolate ligands with molecular oxygen is reported. These reactions result in the formation of the corresponding Roussin's red esters along with thiolate oxidation. This reactivity is contrasted with that previously reported for {Fe(NO)2}10 complexes.

Graphical abstract: Dioxygen mediated conversion of {Fe(NO)2}9 dinitrosyl iron complexes to Roussin's red esters

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The article was received on 15 Jan 2013, accepted on 24 Apr 2013 and first published on 25 Apr 2013


Article type: Communication
DOI: 10.1039/C3CC40352A
Citation: Chem. Commun., 2013,49, 5550-5552
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    Dioxygen mediated conversion of {Fe(NO)2}9 dinitrosyl iron complexes to Roussin's red esters

    J. Fitzpatrick, H. Kalyvas, J. Shearer and E. Kim, Chem. Commun., 2013, 49, 5550
    DOI: 10.1039/C3CC40352A

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