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Issue 3, 2013
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Unique properties of chiral biaryl-based secondary amine catalysts for asymmetric enamine catalysis

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Abstract

A series of biaryl-based secondary amine catalysts with various functional groups have been designed as new chiral amine catalysts. These chiral organocatalysts have been successfully applied to several asymmetric reactions via enamine intermediates and exhibited unique reactivity and selectivity in comparison with proline and its derivatives.

Graphical abstract: Unique properties of chiral biaryl-based secondary amine catalysts for asymmetric enamine catalysis

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Publication details

The article was received on 27 Sep 2012, accepted on 28 Nov 2012 and first published on 29 Nov 2012


Article type: Minireview
DOI: 10.1039/C2SC21612D
Citation: Chem. Sci., 2013,4, 907-915
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    Unique properties of chiral biaryl-based secondary amine catalysts for asymmetric enamine catalysis

    T. Kano and K. Maruoka, Chem. Sci., 2013, 4, 907
    DOI: 10.1039/C2SC21612D

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