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Issue 10, 2012
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Hybrid structure of zinc oxide nanorods and three dimensional graphene foam for supercapacitor and electrochemical sensor applications

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Abstract

A hybrid structure of zinc oxide (ZnO) on three dimensional (3D) graphene foam has been synthesized by chemical vapor deposition (CVD) growth of graphene followed by a facial in situ precipitation of ZnO nanorods under hydrothermal conditions. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) are used to characterize the morphology and structure of graphene/ZnO hybrids. The results show that the ZnO nanorods have high crystallinity and cluster uniformly on graphene skeleton to form flower-like nanostructures. Serving as a free-standing electrode, the electrochemical and biosensing performance of graphene/ZnO hybrids are studied by cyclic voltammetry, electrochemical impedance spectroscopy, galvanostatic charge–discharge and amperometric measurements. It is found that the graphene/ZnO hybrids display superior capacitive performance with high specific capacitance (∼400 F g−1) as well as excellent cycle life, making them suitable for high-performance energy storage applications. Furthermore, the graphene/ZnO hybrids exhibit high sensitivity for detection of [Fe(CN)6]3+ and dopamine, with the extrapolated lower detection limits of ∼1.0 μM and ∼10.0 nM respectively. These results demonstrate the potential of free-standing graphene/ZnO hybrid electrodes for the development of highly sensitive electrochemical sensors.

Graphical abstract: Hybrid structure of zinc oxide nanorods and three dimensional graphene foam for supercapacitor and electrochemical sensor applications

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Publication details

The article was received on 14 Dec 2011, accepted on 28 Feb 2012 and first published on 02 Mar 2012


Article type: Paper
DOI: 10.1039/C2RA01295B
Citation: RSC Adv., 2012,2, 4364-4369
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    Hybrid structure of zinc oxide nanorods and three dimensional graphene foam for supercapacitor and electrochemical sensor applications

    X. Dong, Y. Cao, J. Wang, M. B. Chan-Park, L. Wang, W. Huang and P. Chen, RSC Adv., 2012, 2, 4364
    DOI: 10.1039/C2RA01295B

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