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Issue 6, 2012
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A thermodynamic analysis of methanation reactions of carbon oxides for the production of synthetic natural gas

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Abstract

Synthetic natural gas (SNG) can be obtained via methanation of synthesis gas (syngas). Many thermodynamic reaction details involved in this process are not yet fully understood. In this paper, a comprehensive thermodynamic analysis of reactions occurring in the methanation of carbon oxides (CO and CO2) is conducted using the Gibbs free energy minimization method. The equilibrium constants of eight reactions involved in the methanation reactions were calculated at different temperatures. The effects of temperature, pressure, ratio of H2/CO (and H2/CO2), and the addition of other compounds (H2O, O2, CH4, and C2H4) in the feed gas (syngas) on the conversion of CO and CO2, CH4 selectivity and yield, as well as carbon deposition, were carefully investigated. In addition, experimental data obtained on commercial Ni-based catalysts for CO methanation and three cases adopted from the literature were compared with the thermodynamic calculations. It is found that low temperature, high pressure, and a large H2/CO (and H2/CO2) ratio are favourable for the methanation reactions. Adding steam into the feed gas could alleviate the carbon deposition to a large extent. Trace amounts of O2 in syngas is unfavourable for SNG generation although it can lower carbon deposition. Additional CH4 in the feed gas almost has no influence on the CO conversion and CH4 yield, but it leads to the increase of carbon formed. Introduction of a small amount of C2H4, a representative of hydrocarbons in syngas, results in low CH4 yield and serious carbon deposition although it does not affect CO conversion. CO is relatively easy to hydrogenated compared to CO2 at the same reaction conditions. The comparison of thermodynamic calculations with experimental results demonstrated that the Gibbs free energy minimization method is significantly effective for understanding the reactions occurring in methanation and helpful for the development of catalysts and processes for the production of SNG.

Graphical abstract: A thermodynamic analysis of methanation reactions of carbon oxides for the production of synthetic natural gas

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Publication details

The article was received on 24 Aug 2011, accepted on 07 Dec 2011 and first published on 30 Jan 2012


Article type: Paper
DOI: 10.1039/C2RA00632D
Citation: RSC Adv., 2012,2, 2358-2368
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    A thermodynamic analysis of methanation reactions of carbon oxides for the production of synthetic natural gas

    J. Gao, Y. Wang, Y. Ping, D. Hu, G. Xu, F. Gu and F. Su, RSC Adv., 2012, 2, 2358
    DOI: 10.1039/C2RA00632D

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