Issue 2, 2012
From the journal:

RSC Advances

Ligand-free Hiyama cross-coupling reaction catalyzed by palladium on carbon†

Takayoshi Yanase,a   Yasunari Monguchia  and  Hironao Sajiki*a  

* Corresponding authors

a Laboratory of Organic Chemistry, Gifu Pharmaceutical University, 1-25-4 Daigaku-nishi, Gifu, Japan
E-mail: sajiki@gifu-pu.ac.jp
Fax: (+) 81-58-230-8105

Abstract

A ligand-free Pd/C-catalyzed Hiyama cross-coupling reaction has been developed. A variety of aryl bromides were efficiently cross-coupled with aryltriethoxysilanes with only 0.5 mol% of 5% Pd/C. The protocol would be practical for use as an economical synthetic method for the construction of biphenyl derivatives.

Graphical abstract: Ligand-free Hiyama cross-coupling reaction catalyzed by palladium on carbon

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Article information

DOI
https://doi.org/10.1039/C1RA00776A
Article type
Paper
Submitted
23 Sep 2011
Accepted
27 Sep 2011
First published
14 Nov 2011

RSC Adv., 2012,2, 590-594

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Ligand-free Hiyama cross-coupling reaction catalyzed by palladium on carbon

T. Yanase, Y. Monguchi and H. Sajiki, RSC Adv., 2012, 2, 590 DOI: 10.1039/C1RA00776A

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