Issue 15, 2012

Ruthenium catalysed one-pot synthesis of S-allyl and cinnamyl dithiocarbamates using allyl and cinnamyl acetates in water

Abstract

A convenient and efficient procedure for the synthesis of S-allyl/cinnamyl dithiocarbamates has been developed by a one-pot reaction of allyl/cinnamyl acetate, carbon disulfide and amine in presence of Ru(acac)3 in water. A variety of functionalized dithiocarbamates have been obtained by this procedure in high yields. The reaction proceeds via a catalytic Ru(II) species, generated in situ during the reaction.

Graphical abstract: Ruthenium catalysed one-pot synthesis of S-allyl and cinnamyl dithiocarbamates using allyl and cinnamyl acetates in water

Supplementary files

Article information

Article type
Paper
Submitted
03 May 2012
Accepted
10 May 2012
First published
14 Jun 2012

RSC Adv., 2012,2, 6329-6335

Ruthenium catalysed one-pot synthesis of S-allyl and cinnamyl dithiocarbamates using allyl and cinnamyl acetates in water

S. Ahammed, A. Saha and B. C. Ranu, RSC Adv., 2012, 2, 6329 DOI: 10.1039/C2RA20856C

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