Issue 48, 2012
From the journal:

Organic & Biomolecular Chemistry

Synthesis of allenamides by Pd-catalyzed coupling of 3-alkoxycarbonyloxy ynamides or 1-alkoxycarbonyloxy allenamides with arylboronic acids†

Jian Cao,*a   Yulong Kong,a   Yuan Deng,a   Guoqiao Lai,*a   Yuming Cui,a   Ziqiang Hua  and  Guanhai Wanga  

* Corresponding authors

a Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, Wenyi Road 222, Hangzhou 310012, P. R. China
E-mail: caojianhznu@yahoo.cn

Abstract

An efficient palladium-catalyzed method is reported for the synthesis of multi-substituted allenamides by Suzuki–Miyaura cross-coupling reaction between easily prepared 3-alkoxycarbonyloxy ynamides or 1-alkoxycarbonyloxy allenamides and arylboronic acids.

Graphical abstract: Synthesis of allenamides by Pd-catalyzed coupling of 3-alkoxycarbonyloxy ynamides or 1-alkoxycarbonyloxy allenamides with arylboronic acids

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Article information

DOI
https://doi.org/10.1039/C2OB26727F
Article type
Paper
Submitted
01 Sep 2012
Accepted
15 Oct 2012
First published
17 Oct 2012

Org. Biomol. Chem., 2012,10, 9556-9561

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Synthesis of allenamides by Pd-catalyzed coupling of 3-alkoxycarbonyloxy ynamides or 1-alkoxycarbonyloxy allenamides with arylboronic acids

J. Cao, Y. Kong, Y. Deng, G. Lai, Y. Cui, Z. Hu and G. Wang, Org. Biomol. Chem., 2012, 10, 9556 DOI: 10.1039/C2OB26727F

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