Issue 17, 2012

Nickel-catalyzed C–P coupling of aryl mesylates and tosylates with H(O)PR1R2

Abstract

A method was developed for the nickel-catalyzed phosphonylation of aryl mesylates and tosylates with H(O)PR1R2. To the best of our knowledge, this is the first example of nickel-catalyzed C–P coupling of aryl mesylates and tosylates. Most of the substrates gave moderate to good yields under our catalytic system.

Graphical abstract: Nickel-catalyzed C–P coupling of aryl mesylates and tosylates with H(O)PR1R2

Supplementary files

Article information

Article type
Paper
Submitted
31 Jan 2012
Accepted
19 Feb 2012
First published
21 Feb 2012

Org. Biomol. Chem., 2012,10, 3500-3505

Nickel-catalyzed C–P coupling of aryl mesylates and tosylates with H(O)PR1R2

C. Shen, G. Yang and W. Zhang, Org. Biomol. Chem., 2012, 10, 3500 DOI: 10.1039/C2OB25225B

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