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Issue 12, 2012
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Modeling, simulation, and design criteria for photoelectrochemical water-splitting systems

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Abstract

A validated multi-physics numerical model that accounts for charge and species conservation, fluid flow, and electrochemical processes has been used to analyze the performance of solar-driven photoelectrochemical water-splitting systems. The modeling has provided an in-depth analysis of conceptual designs, proof-of-concepts, feasibility investigations, and quantification of performance. The modeling has led to the formulation of design guidelines at the system and component levels, and has identified quantifiable gaps that warrant further research effort at the component level. The two characteristic generic types of photoelectrochemical systems that were analyzed utilized: (i) side-by-side photoelectrodes and (ii) back-to-back photoelectrodes. In these designs, small electrode dimensions (mm to cm range) and large electrolyte heights were required to produce small overall resistive losses in the system. Additionally, thick, non-permeable separators were required to achieve acceptably low rates of product crossover.

Graphical abstract: Modeling, simulation, and design criteria for photoelectrochemical water-splitting systems

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Publication details

The article was received on 15 Aug 2012, accepted on 28 Sep 2012, published on 01 Oct 2012 and first published online on 01 Oct 2012


Article type: Paper
DOI: 10.1039/C2EE23187E
Citation: Energy Environ. Sci., 2012,5, 9922-9935
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    Modeling, simulation, and design criteria for photoelectrochemical water-splitting systems

    S. Haussener, C. Xiang, J. M. Spurgeon, S. Ardo, N. S. Lewis and A. Z. Weber, Energy Environ. Sci., 2012, 5, 9922
    DOI: 10.1039/C2EE23187E

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