Issue 38, 2012
From the journal:

Dalton Transactions

Two hybrid polyoxometalate-pillared metal–organic frameworks†

Xiao-Yuan Wu,ab   Qi-Kai Zhang,ab   Xiao-Fei Kuang,ab   Wen-bin Yang,ab   Rong-Min Yuab  and  Can-Zhong Lu*ab  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, China
E-mail: czlu@ fjirsm.ac.cn
Fax: (+86)-591-83714946
Tel: (+86)-591-83705794

b Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, China

Abstract

Two polyoxometalate-pillared 3D compounds, {Cu5(2-ptz)6(H2O)4(SiW12O40)}·4H2O 1 and {Cu9(2-ptz)12(H2O)6(PMo12O40)2}·H2O 2 (2-ptz = 5-(2-pyridyl)tetrazole) have been constructed based on different polyoxometalate anions, and copper–organic coordination polymer sheets by a hydrothermal method. Magnetic investigations reveal that both 1 and 2 exhibit antiferromagnetic coupling between the CuII ions. Structural studies show the compound 1 exhibits a typical pcu-type net with the Schälfli symbol of {412·63}, and that compound 2 is a (3,4,6)-connected framework with novel {44·610·10}{63}2{65·8} topology which has not been reported to date.

Graphical abstract: Two hybrid polyoxometalate-pillared metal–organic frameworks

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Article information

DOI
https://doi.org/10.1039/C2DT30920C
Article type
Paper
Submitted
27 Apr 2012
Accepted
22 Jun 2012
First published
25 Jun 2012

Dalton Trans., 2012,41, 11783-11787

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Two hybrid polyoxometalate-pillared metal–organic frameworks

X. Wu, Q. Zhang, X. Kuang, W. Yang, R. Yu and C. Lu, Dalton Trans., 2012, 41, 11783 DOI: 10.1039/C2DT30920C

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