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Issue 26, 2012
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Reaction of carbon dioxide with a palladiumalkyl complex supported by a bis-NHC framework

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Abstract

The reactivity of a dimethyl palladium complex supported by a dicarbene chelate (MDCMes)PdMe2 towards CO2 has been investigated. In the presence of trace H2O, this reaction yields the corresponding methyl bicarbonate complex (MDCMes)PdMe(O2COH), which goes on to give the corresponding κ2-carbonato complex upon crystallization (MDCMes)Pd(CO3). This chemistry, as well as related protonolysis by acetic acid was monitored by a combination of techniques including React-IR spectroscopy.

Graphical abstract: Reaction of carbon dioxide with a palladium–alkyl complex supported by a bis-NHC framework

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Publication details

The article was received on 23 Mar 2012, accepted on 18 May 2012 and first published on 30 May 2012


Article type: Paper
DOI: 10.1039/C2DT30676J
Citation: Dalton Trans., 2012,41, 7977-7983
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    Reaction of carbon dioxide with a palladiumalkyl complex supported by a bis-NHC framework

    P. W. G. Ariyananda, G. P. A. Yap and J. Rosenthal, Dalton Trans., 2012, 41, 7977
    DOI: 10.1039/C2DT30676J

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