Reaction of carbon dioxide with a palladium–alkyl complex supported by a bis-NHC framework

Piyal W. G. Ariyananda; Glenn P. A. Yap; Joel Rosenthal

doi:10.1039/C2DT30676J

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Dalton Transactions

Issue 26, 2012

The international journal for inorganic, organometallic and bioinorganic chemistry

Impact Factor 3.838 48 Issues per Year Indexed in MEDLINE

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Reaction of carbon dioxide with a palladium–alkyl complex supported by a bis-NHC framework

Piyal W. G. Ariyananda,^a Glenn P. A. Yap^a and Joel Rosenthal*^a

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Department of Chemistry and Biochemistry, University of Delaware, Newark, USA
E-mail: rosenthal@mail.chem.udel.edu

Dalton Trans., 2012,41, 7977-7983

DOI: 10.1039/C2DT30676J
Received 23 Mar 2012, Accepted 18 May 2012
First published online 30 May 2012

This article is part of themed collection: New Talent: Americas

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Abstract
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The reactivity of a dimethyl palladium complex supported by a dicarbene chelate (MDC^Mes)PdMe₂ towards CO₂ has been investigated. In the presence of trace H₂O, this reaction yields the corresponding methyl bicarbonate complex (MDC^Mes)PdMe(O₂COH), which goes on to give the corresponding κ²-carbonato complex upon crystallization (MDC^Mes)Pd(CO₃). This chemistry, as well as related protonolysis by acetic acid was monitored by a combination of techniques including React-IR spectroscopy.

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