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Issue 23, 2012
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Complexes with 3-(pyridin-2-yl)imidazo[1,5-a]pyridine ligands by spontaneous dimerization of pyridine-2-carboxaldehyde within the coordination sphere of manganese(II) in a one-pot reaction

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Abstract

Condensation of two molecules of pyridine-2-carboxaldehyde (pyca), in the presence of MnCl2 and ammonium diethyldithiophosphate, produced, in a one-pot reaction, Mn(II) complexes containing 3-(pyridin-2-yl)imidazo[1,5-a]pyridines as κ2(N,N) chelate ligands which could be easily separated from the metal, this being a convenient way to pyridyl-aza-indolizine heterocycles.

Graphical abstract: Complexes with 3-(pyridin-2-yl)imidazo[1,5-a]pyridine ligands by spontaneous dimerization of pyridine-2-carboxaldehyde within the coordination sphere of manganese(ii) in a one-pot reaction

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Publication details

The article was received on 24 Feb 2012, accepted on 16 Apr 2012 and first published on 17 Apr 2012


Article type: Paper
DOI: 10.1039/C2DT30453H
Citation: Dalton Trans., 2012,41, 7041-7046
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    Complexes with 3-(pyridin-2-yl)imidazo[1,5-a]pyridine ligands by spontaneous dimerization of pyridine-2-carboxaldehyde within the coordination sphere of manganese(II) in a one-pot reaction

    C. M. Álvarez, L. Álvarez-Miguel, R. García-Rodríguez and D. Miguel, Dalton Trans., 2012, 41, 7041
    DOI: 10.1039/C2DT30453H

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