Group 11 complexes containing the [C5(CN)5]−ligand; ‘coordination-analogues’ of molecular organometallic systems†
Abstract
The reactions of Na[C5(CN)5] (Na[1]) with group 11 phosphine complexes [(P)nMCl] (M = Cu, Ag, Au, P = Ph3P; M = Cu, P = dppe (Ph2PCH2CH2PPh2)] give a range of compounds containing the pentacyanocyclopentadienide