Issue 17, 2012
From the journal:

Dalton Transactions

Monomeric organoantimony(iii) sulphide and selenide with terminal Sb–E bond (E = S, Se). Synthesis, structure and theoretical consideration†

Petr Šimon,ab   Roman Jambor,a   Aleš Růžička,a   Antonín Lyčka,c   Frank De Proftd  and  Libor Dostál*a  

* Corresponding authors

a Department of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, Studentská 573, Pardubice, Czech Republic
E-mail: libor.dostal@upce.cz
Fax: +420466037068
Tel: +420466037163

b Institute of Microbiology, Centre of Biocatalysis and Biotransformation, Academy of Sciences of the Czech Republic, Vídeňská 1083, CZ-142 20 Prague, Czech Republic

c Research Institute for Organic Syntheses, Rybitví 296, CZ-533 54 Pardubice, Czech Republic

d Eenheid Algemene Chemie (ALGC), Vrije Universiteit Brussel (VUB), Pleinlaan 2, B-1050 Brussels, Belgium

Abstract

NCN chelated monomeric chalcogenides, LSbE (E = S (1), Se (2), L = 2,6-bis[N-(2′,6′-dimethylphenyl)ketimino]phenyl), were synthesized and characterized with the help of elemental analysis, NMR spectroscopy and single-crystal X-ray diffraction analyses. The terminal Sb–E (E = S, Se) bonds in 1 and 2 were subjected to theoretical investigation and the results are compared with the hypothetical molecules, PhSb[double bond, length as m-dash]E (E = S, Se, Te), and earlier reported analogues.

Graphical abstract: Monomeric organoantimony(iii) sulphide and selenide with terminal Sb–E bond (E = S, Se). Synthesis, structure and theoretical consideration

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Article information

DOI
https://doi.org/10.1039/C2DT30146F
Article type
Communication
Submitted
19 Jan 2012
Accepted
08 Mar 2012
First published
09 Mar 2012

Dalton Trans., 2012,41, 5140-5143

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Monomeric organoantimony(III) sulphide and selenide with terminal Sb–E bond (E = S, Se). Synthesis, structure and theoretical consideration

P. Šimon, R. Jambor, A. Růžička, A. Lyčka, F. De Proft and L. Dostál, Dalton Trans., 2012, 41, 5140 DOI: 10.1039/C2DT30146F

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