[Ni(C17H20N4)4][H5PMoVI8VIV4O40(VIVO)2]·8H2O: confinement of heteropoly anions in Ni-containing rigid concave surfaces with high catalytic activity in the oxidation of styrene

Jie Fu; Haixia Sun; Yan Xu; Congling Wang; Dunru Zhu; Qi Sun; Hongke Liu

doi:10.1039/C2CE25419K

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[Ni(C₁₇H₂₀N₄)₄][H₅PMo^VI₈V^IV₄O₄₀(V^IVO)₂]·8H₂O: confinement of heteropoly anions in Ni-containing rigid concave surfaces with high catalytic activity in the oxidation of styrene†

Jie Fu,^a Haixia Sun,^b Yan Xu,*^a Congling Wang,^a Dunru Zhu,^a Qi Sun^c and Hongke Liu^b

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* Corresponding authors

^a College of Chemistry and Chemical Engineering, State Key Laboratory of Materials-oriented Chemical Engineering, Nanjing University of Technology, Nanjing, P. R. China
E-mail: yanxu@njut.edu.cn

^b Jiangsu Province Key Laboratory of Biofunctional Material, School of Chemistry and Environmental Science, Nanjing Normal University, Nanjing 210046, P. R. China
E-mail: liuhongke@njnu.edu.cn

^c Institute of Functionalized Chemistry Materials, Faculty of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian Liaoning, 116029, P. R. China

Abstract

An organic–inorganic hybrid solid material, [Ni(m-bitmb)₄][H₅PMo^VI₈V^IV₄O₄₀(V^IVO)₂]·8H₂O (m-bitmb = 1, 3-bis (1-imidazol-1-ylmethyl)-2,4,6-trimethylbenzene) 1, constructed from a bi-capped Keggin structural anion [H₅PMo^VI₈V^IV₄O₄₀(V^IVO)₂]²⁻ (abbreviated as PMo₈V₆), and saddle shape cluster [Ni(m-bitmb)₄]²⁺, has been synthesized. Compound 1 is also demonstrated to be a high activity for benzaldehyde in the oxidation of styrene.

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Article information

DOI: https://doi.org/10.1039/C2CE25419K
Article type: Communication
Submitted: 07 Feb 2012
Accepted: 10 May 2012
First published: 10 May 2012

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CrystEngComm, 2012,14, 5148-5150

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[Ni(C₁₇H₂₀N₄)₄][H₅PMo^VI₈V^IV₄O₄₀(V^IVO)₂]·8H₂O: confinement of heteropoly anions in Ni-containing rigid concave surfaces with high catalytic activity in the oxidation of styrene

J. Fu, H. Sun, Y. Xu, C. Wang, D. Zhu, Q. Sun and H. Liu, CrystEngComm, 2012, 14, 5148 DOI: 10.1039/C2CE25419K

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