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Issue 20, 2012
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Remote halogen switch of amine hydrophilicity

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Abstract

Bromide and iodide anions switch hydrogen-bonding patterns in otherwise isostructural dimethanol solvates N-methyl-1,4-diazabicyclo[2.2.2]octanium bromide (dabcoCH3Br·2CH3OH) and analogous iodide (dabcoCH3I·2CH3OH), both synthesized in the high-pressure version of the Menshutkin reaction at 1.2 and 2.4 GPa, respectively. The magnitudes of the high pressure triggering these reactions correspond to identical molecular volumes of both solvates.

Graphical abstract: Remote halogen switch of amine hydrophilicity

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Publication details

The article was received on 21 Mar 2012, accepted on 22 Jun 2012 and first published on 03 Aug 2012


Article type: Communication
DOI: 10.1039/C2CE25401H
Citation: CrystEngComm, 2012,14, 6374-6376
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    Remote halogen switch of amine hydrophilicity

    M. Andrzejewski, A. Olejniczak and A. Katrusiak, CrystEngComm, 2012, 14, 6374
    DOI: 10.1039/C2CE25401H

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