Issue 17, 2012
From the journal:

CrystEngComm

Direct observation of conformational change of adipate dianions encapsulated in water clusters†

Geng-Geng Luo,*a   Dong-Liang Wu,a   Ji-Huai Wu,a   Jiu-Xu Xia,a   Li Liua  and  Jing-Cao Daia  

* Corresponding authors

a Institute of Materials Physical Chemistry, College of Materials Science and Engineering, Huaqiao University, Xiamen, China
E-mail: ggluo@hqu.edu.cn

Abstract

Two novel hydrated adipate dianions including (adip)aaa·(H2O)16 and (adip)gag·(H2O)20 (adip = dianion of adipic acid, aaa = anti–anti–anti and gag = gauche–anti–gauche) were observed in two silver-based cationic hosts. They not only reveal the precise arrangement of water clusters around the carboxylate groups and aliphatic chains of adipate dianions, but show the conformational change of adipate dianions in water clusters, for the first time.

Graphical abstract: Direct observation of conformational change of adipate dianions encapsulated in water clusters

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Article information

DOI
https://doi.org/10.1039/C2CE25200G
Article type
Communication
Submitted
13 Feb 2012
Accepted
03 Jun 2012
First published
07 Jun 2012

CrystEngComm, 2012,14, 5377-5380

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Direct observation of conformational change of adipate dianions encapsulated in water clusters

G. Luo, D. Wu, J. Wu, J. Xia, L. Liu and J. Dai, CrystEngComm, 2012, 14, 5377 DOI: 10.1039/C2CE25200G

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