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Issue 100, 2012
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Iron promoted conjugate addition: implication of the six-centered mechanism based on the isolation of the iron-enolate intermediate

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Abstract

Treatment of (η1-mesityl)2Fe(κ2-TMEDA) (1′) with an α,β-unsaturated carbonyl compound results in 1,4-addition of the mesityl group to give an iron enolate 3 quantitatively. The Z-configuration of the enolate suggested the six-centered mechanism for the conjugate addition.

Graphical abstract: Iron promoted conjugate addition: implication of the six-centered mechanism based on the isolation of the iron-enolate intermediate

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Publication details

The article was received on 01 Oct 2012, accepted on 01 Nov 2012 and first published on 02 Nov 2012


Article type: Communication
DOI: 10.1039/C2CC37144H
Citation: Chem. Commun., 2012,48, 12231-12233
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    Iron promoted conjugate addition: implication of the six-centered mechanism based on the isolation of the iron-enolate intermediate

    D. Noda, Y. Sunada, T. Hatakeyama, M. Nakamura and H. Nagashima, Chem. Commun., 2012, 48, 12231
    DOI: 10.1039/C2CC37144H

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