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Issue 1, 2013
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Chemically orthogonal trifunctional Janus beads by photochemical “sandwich” microcontact printing

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Abstract

The combination of topographic and chemical orthogonality on polymer particles by site selective immobilization of functional thiols via thiol–ene chemistry provides a trifunctional particle surface with azide and acid functionalities on opposing poles and alkenes in the equatorial area. These Janus beads are accessible for site selective orthogonal chemical reactions as well as biomolecular recognition on the same particle.

Graphical abstract: Chemically orthogonal trifunctional Janus beads by photochemical “sandwich” microcontact printing

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Publication details

The article was received on 05 Sep 2012, accepted on 05 Nov 2012 and first published on 06 Nov 2012


Article type: Communication
DOI: 10.1039/C2CC36483B
Citation: Chem. Commun., 2013,49, 63-65
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    Chemically orthogonal trifunctional Janus beads by photochemical “sandwich” microcontact printing

    T. Kaufmann, C. Wendeln, M. T. Gokmen, S. Rinnen, M. M. Becker, H. F. Arlinghaus, F. Du Prez and B. J. Ravoo, Chem. Commun., 2013, 49, 63
    DOI: 10.1039/C2CC36483B

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