Jump to main content
Jump to site search

Issue 87, 2012
Previous Article Next Article

Rhodium(III)-catalyzed allylic C–H bond amination. Synthesis of cyclic amines from ω-unsaturated N-sulfonylamines

Author affiliations

Abstract

For the first time, intramolecular allylic amination was conducted using rhodium(III) according to an “inner-sphere” type mechanism with amines activated by only one electron-withdrawing group. The activation of C(sp3)–H bonds was chemoselective and allows the access to a variety of substituted cyclic amines such as pyrrolidines and piperidines.

Graphical abstract: Rhodium(iii)-catalyzed allylic C–H bond amination. Synthesis of cyclic amines from ω-unsaturated N-sulfonylamines

Back to tab navigation

Supplementary files

Publication details

The article was received on 21 Aug 2012, accepted on 10 Sep 2012 and first published on 28 Sep 2012


Article type: Communication
DOI: 10.1039/C2CC36067E
Citation: Chem. Commun., 2012,48, 10745-10747
  •   Request permissions

    Rhodium(III)-catalyzed allylic C–H bond amination. Synthesis of cyclic amines from ω-unsaturated N-sulfonylamines

    T. Cochet, V. Bellosta, D. Roche, J. Ortholand, A. Greiner and J. Cossy, Chem. Commun., 2012, 48, 10745
    DOI: 10.1039/C2CC36067E

Search articles by author

Spotlight

Advertisements