Issue 39, 2013
From the journal:

Chemical Communications

N–H activation of hydrazines by a heterobimetallic Zr–Co complex: promotion of one-electron chemistry at Zr†‡

J. W. Napoline,a   Mark W. Bezpalko,a   Bruce M. Foxmana  and  Christine M. Thomas*a  

* Corresponding authors

a Department of Chemistry, Brandeis University, 415 South Street, Waltham, USA
E-mail: thomasc@brandeis.edu
Fax: +1 781736-2516
Tel: +1 781736-2576

Abstract

A tris(phosphino)amide-ligated Zr–Co heterobimetallic complex has been shown to activate N–H bonds of hydrazine derivatives via a proton-coupled electron transfer process. Such reactivity is highly unusual for an early metal such as Zr, but is promoted by the adjacent redox active Co atom.

Graphical abstract: N–H activation of hydrazines by a heterobimetallic Zr–Co complex: promotion of one-electron chemistry at Zr

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Article information

DOI
https://doi.org/10.1039/C2CC35594A
Article type
Communication
Submitted
01 Aug 2012
Accepted
28 Sep 2012
First published
01 Oct 2012
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2013,49, 4388-4390

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N–H activation of hydrazines by a heterobimetallic Zr–Co complex: promotion of one-electron chemistry at Zr

J. W. Napoline, M. W. Bezpalko, B. M. Foxman and C. M. Thomas, Chem. Commun., 2013, 49, 4388 DOI: 10.1039/C2CC35594A

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