Issue 85, 2012
From the journal:

Chemical Communications

Chiral recognition in metal–organic frameworks studied by solid-state NMRspectroscopy using chiral solvating agents†

Herbert C. Hoffmann,a   Silvia Paasch,a   Philipp Müller,b   Irena Senkovska,b   Mohan Padmanaban,c   Frank Glorius,c   Stefan Kaskelb  and  Eike Brunner*a  

* Corresponding authors

a TU Dresden, Fachrichtung Chemie und Lebensmittelchemie, Bioanalytische Chemie, 01062 Dresden, Germany
E-mail: eike.brunner@tu-dresden.de
Fax: +49 351 463 37188
Tel: +49 351 463 37152

b TU Dresden, Fachrichtung Chemie und Lebensmittelchemie, Anorganische Chemie I, 01062 Dresden, Germany

c Westfälische Wilhelms-Universität Münster, Organisch-Chemisches Institut, 48149 Münster, Germany

Abstract

Recently, we have described the synthesis of chiral metal–organic frameworks iPr-ChirUMCM-1 and Bn-ChirUMCM-1 and their use in enantioselective separation. Here, we demonstrate for the first time the use of a chiral solvating agent (1-phenyl-2,2,2-trifluoroethanol, TFPE) for chiral recognition in iPr-ChirUMCM-1 and Bn-ChirUMCM-1 by means of solid-state13C NMR spectroscopy.

Graphical abstract: Chiral recognition in metal–organic frameworks studied by solid-state NMR spectroscopy using chiral solvating agents

  • This article is part of the themed collection: Chirality
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Article information

DOI
https://doi.org/10.1039/C2CC35366K
Article type
Communication
Submitted
25 Jul 2012
Accepted
15 Aug 2012
First published
16 Aug 2012

Chem. Commun., 2012,48, 10484-10486

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Chiral recognition in metal–organic frameworks studied by solid-state NMR spectroscopy using chiral solvating agents

H. C. Hoffmann, S. Paasch, P. Müller, I. Senkovska, M. Padmanaban, F. Glorius, S. Kaskel and E. Brunner, Chem. Commun., 2012, 48, 10484 DOI: 10.1039/C2CC35366K

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