Issue 76, 2012
From the journal:

Chemical Communications

Copper-catalyzed conversion of aryl and heteroaryl bromides into the corresponding chlorides†

Xiujuan Feng,*a   Yiping Qu,a   Yanlei Han,a   Xiaoqiang Yu,a   Ming Bao*a  and  Yoshinori Yamamotoab  

* Corresponding authors

a State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116023, China
E-mail: mingbao@dlut.edu.cn, fengxiujuan@dlut.edu.cn
Fax: +86-0411-84986180
Tel: +86-0411-84986180

b WPI-AIMR (WPI-Advanced Institute for Materials Research), Tohoku University, Sendai 980-8577, Japan

Abstract

An efficient method for the synthesis of aryl and heteroaryl chlorides is described. The reactions of aryl and heteroaryl bromides with tetramethylammonium chloride proceeded smoothly in the presence of a copper catalyst under mild reaction conditions to produce the corresponding chlorides in satisfactory to excellent yields.

Graphical abstract: Copper-catalyzed conversion of aryl and heteroaryl bromides into the corresponding chlorides

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Article information

DOI
https://doi.org/10.1039/C2CC34944B
Article type
Communication
Submitted
11 Jul 2012
Accepted
02 Aug 2012
First published
02 Aug 2012

Chem. Commun., 2012,48, 9468-9470

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Copper-catalyzed conversion of aryl and heteroaryl bromides into the corresponding chlorides

X. Feng, Y. Qu, Y. Han, X. Yu, M. Bao and Y. Yamamoto, Chem. Commun., 2012, 48, 9468 DOI: 10.1039/C2CC34944B

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