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Issue 73, 2012
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Strictly diastereocontrolled photocyclodimerization of 2-anthracenecarboxylates tethered to cyclic tetrasaccharides

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Abstract

Photocyclodimerization of 2-anthracenecarboxylate tethered to a cyclic nigerosylnigerose scaffold gave a single chiral cyclodimer (out of two achiral and two chiral stereoisomers) in 99% optical and 96% chemical yields, achieving the ultimate stereocontrol of the supramolecular photochirogenesis in aqueous solution at 25 °C.

Graphical abstract: Strictly diastereocontrolled photocyclodimerization of 2-anthracenecarboxylates tethered to cyclic tetrasaccharides

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Publication details

The article was received on 09 Jul 2012, accepted on 25 Jul 2012 and first published on 25 Jul 2012


Article type: Communication
DOI: 10.1039/C2CC34880B
Citation: Chem. Commun., 2012,48, 9156-9158
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    Strictly diastereocontrolled photocyclodimerization of 2-anthracenecarboxylates tethered to cyclic tetrasaccharides

    G. Fukuhara, T. Nakamura, Y. Kawanami, C. Yang, T. Mori, H. Hiramatsu, Y. Dan-oh, K. Tsujimoto and Y. Inoue, Chem. Commun., 2012, 48, 9156
    DOI: 10.1039/C2CC34880B

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