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Issue 71, 2012
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A pillared metal–organic framework incorporated with 1,2,3-triazole moieties exhibiting remarkable enhancement of CO2 uptake

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Abstract

The replacement of the pillar ligand, 4,4′-bipyridine, in the prototypal pillared MOF, MOF-508, with the custom-designed ligand, 4,4′-(2H-1,2,3-triazole-2,4-diyl)dipyridine, affords a porous metal–triazolate framework, MTAF-3, which demonstrates remarkable enhancement of CO2 uptake capacity by a factor of ∼3 compared to the parent MOF-508.

Graphical abstract: A pillared metal–organic framework incorporated with 1,2,3-triazole moieties exhibiting remarkable enhancement of CO2 uptake

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Publication details

The article was received on 19 Jun 2012, accepted on 21 Jul 2012 and first published on 23 Jul 2012


Article type: Communication
DOI: 10.1039/C2CC34380K
Citation: Chem. Commun., 2012,48, 8898-8900
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    A pillared metal–organic framework incorporated with 1,2,3-triazole moieties exhibiting remarkable enhancement of CO2 uptake

    W. Gao, W. Yan, R. Cai, K. Williams, A. Salas, L. Wojtas, X. Shi and S. Ma, Chem. Commun., 2012, 48, 8898
    DOI: 10.1039/C2CC34380K

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